Calorie

The calorie is a unit of energy.[1][2] For historical reasons, two main definitions of "calorie" are in wide use. The large calorie, food calorie, or kilogram calorie was originally defined as the amount of heat needed to raise the temperature of one kilogram of water by one degree Celsius (or one kelvin).[1][3] The small calorie or gram calorie was defined as the amount of heat needed to cause the same increase in one gram of water.[3][4][5][1] Thus, 1 large calorie is equal to 1000 small calories.

"kcal" redirects here; this article is about the unit of energy. For other uses, see KCAL (disambiguation) and Calorie (disambiguation).
A 710-millilitre (24 US fl oz) energy drink with 330 kilocalories

In nutrition and food science, the term calorie and the symbol cal almost always refers to the large unit. It is generally used in publications and package labels to express the energy value of foods in per serving or per weight, recommended dietary caloric intake,[6][7] metabolic rates, etc. Some authors recommend the spelling Calorie and the symbol Cal (both with a capital C) to avoid confusion;[8] however, this convention is often ignored.[6][7][8]

In physics and chemistry the word calorie and its symbol usually refer to the small unit; the large one being called kilocalorie. However, this unit is not officially part of the metric system (SI), and is regarded as obsolete,[2] having been replaced in many uses by the SI unit of energy, the joule (J).[9]

The precise equivalence between calories and joules has varied over the years, but in thermochemistry and nutrition it is now generally assumed that one (small) calorie (thermochemical calorie) is equal to exactly 4.184 J, and therefore one kilocalorie (one large calorie) is 4184 J, or 4.184 kJ.[10][11]

History

The term "calorie" was first introduced by Nicolas Clément, as a unit of heat energy, in lectures on experimental calorimetry during the years 1819–1824.[12] This was the "large" calorie.[2][13][14] The term (written with lowercase "c") entered French and English dictionaries between 1841 and 1867. It comes from Latin calor 'heat'.

The same term was used for the "small" unit by Pierre Antoine Favre (Chemist) and Johann T. Silbermann (Physicist) in 1852. This unit was used by U.S. physician Joseph Howard Raymond, in his classic 1894 textbook A Manual of Human Physiology.[15] He proposed calling the "large" unit "kilocalorie", but the term didn't catch on until some years later.

In 1879, Marcellin Berthelot distinguished between gram-calorie and kilogram-calorie, and proposed using "Calorie", with capital "C", for the large unit.[2] This usage was adopted by Wilbur Olin Atwater, a professor at Wesleyan University, in 1887, in an influential article on the energy content of food.[2][13]

The small calorie (cal) was recognized as a unit of the cm-g-s system (cgs) in 1896,[2][14] alongside the already-existing cgs unit of energy, the erg (first suggested by Clausius in 1864, under the name ergon, and officially adopted in 1882).

Already in 1928 there were serious complaints about the possible confusion arising from the two main definitions of the calorie and whether the notion of using the capital letter to distinguish them was sound.[16]

The small calorie was originally part of the metric system (SI),[10] but it was officially deprecated by the ninth General Conference on Weights and Measures in 1948.[17] in favor of the joule.[9]

The alternate spelling calory is archaic.

Definitions

The "small" calorie is broadly defined as the amount of energy needed to increase the temperature of 1 gram of water by 1 °C (or 1 K, which is the same increment).[4][5] The amount depends on the atmospheric pressure and the starting temperature, and different choices of these parameters have resulted in several different precise definitions of the unit.

NameSymbolConversionsDefinition and notes
Thermochemical caloriecalth ≡ 4.184 J

≈ 0.003964 BTU ≈ 1.162×10−6 kW⋅h ≈ 2.611×1019 eV

 The amount of energy equal to exactly 4.184 J (Joules) and 1 kJ = 0.239 kcal.[18][19][20][11] (a).
4 °C caloriecal4 ≈ 4.204 J

≈ 0.003985 BTU ≈ 1.168×10−6 kW⋅h ≈ 2.624×1019 eV

 The amount of energy required to warm one gram of air-free water from 3.5 to 4.5 °C at standard atmospheric pressure. (c)
15 °C caloriecal15 ≈ 4.1855 J

≈ 0.0039671 BTU ≈ 1.1626×10−6 kW⋅h ≈ 2.6124×1019 eV

 The amount of energy required to warm one gram of air-free water from 14.5 to 15.5 °C at standard atmospheric pressure. (c) Experimental values of this calorie ranged from 4.1852 to 4.1858 J. The CIPM in 1950 published a mean experimental value of 4.1855 J, noting an uncertainty of 0.0005 J.[18]
20 °C caloriecal20 ≈ 4.182 J

≈ 0.003964 BTU ≈ 1.162×10−6 kW⋅h ≈ 2.610×1019 eV

 The amount of energy required to warm one gram of air-free water from 19.5 to 20.5 °C at standard atmospheric pressure. (c)
Mean caloriecalmean ≈ 4.190 J

≈ 0.003971 BTU ≈ 1.164×10−6 kW⋅h ≈ 2.615×1019 eV

 Defined as 1⁄100 of the amount of energy required to warm one gram of air-free water from 0 to 100 °C at standard atmospheric pressure. (c)
International Steam Table calorie (1929) ≈ 4.1868 J

≈ 0.0039683 BTU ≈ 1.1630×10−6 kW⋅h ≈ 2.6132×1019 eV

 Defined as 1⁄860 "international" watt hours = 180⁄43 "international" joules exactly. (b)
International Steam Table calorie (1956)calIT ≡ 4.1868 J

≈ 0.0039683 BTU = 1.1630×10−6 kW⋅h ≈ 2.6132×1019 eV

 Defined as 1.163 mW⋅h = 4.1868 J exactly. This definition was adopted by the Fifth International Conference on Properties of Steam (London, July 1956).[18]
(a) The 'Thermochemical calorie' was defined by Rossini simply as 4.1833 international joules in order to avoid the difficulties associated with uncertainties about the heat capacity of water. It was later redefined as 4.1840 J exactly.[21]
(b) The figure depends on the conversion factor between "international joules" and "absolute" (modern, SI) joules. Using the mean international ohm and volt (1.00049 Ω, 1.00034 V[22]), the "international joule" is about 1.00019 J, using the US international ohm and volt (1.000495 Ω, 1.000330 V) it is about 1.000165 J, giving 4.18684 and 4.18674 J, respectively.
(c) The standard atmospheric pressure can be taken to be 101.325 kPa.

The two definitions most common in older literature appear to be the 15 °C calorie and the thermochemical calorie. Until 1948, the latter was defined as 4.1833 international joules; the current standard of 4.184 J was chosen to have the new thermochemical calorie represent the same quantity of energy as before.[19]

Usage

Nutrition

In a nutritional context, the "large" unit is used almost exclusively. It is generally written "calorie" with lowercase "c" and symbol "cal", even in government publications,[6][7] although the capitalized form "Calorie" (with symbol "Cal") or the name "kilocalorie" (with symbol "kcal") are also used, and may be mandated by law. The SI unit of energy kilojoule (kJ) may be used instead, in legal or scientific contexts. [23][24]

In the United States, most nutritionists prefer the unit kilocalorie to the unit kilojoules, whereas most physiologists prefer to use kilojoules. In the majority of other countries, nutritionists prefer the kilojoule to the kilocalorie.[25]

On nutrition facts labels in the European Union, energy is expressed in both kilojoules and kilocalories.[26] In the United States and Canada, labels use "Calories", referring to the large unit.[27] In China, only kilojoules are given.[28]

Food energy

The unit is most commonly used to express food energy, namely the specific energy (energy per mass) of metabolizing different types of food. For example, fat (lipids) contains 9 kilocalories per gram (kcal/g), while carbohydrates (sugar and starch) and protein contains approximately 4 kcal/g.[29] Alcohol in food contains 7 kcal/g.[30] The "large" unit is also used to express recommended nutritional intake or consumption, as in "calories per day".

Dieting is the practice of eating food in a regulated way to decrease, maintain, or increase body weight, or to prevent and treat diseases such as diabetes and obesity. As weight loss depends on reducing caloric intake, different kinds of calorie-reduced diets have been shown to be generally effective.[31]

Chemistry and physics

In other scientific contexts, the term "calorie" and the symbol "cal" almost always refers to the small unit; the "large" unit being generally called "kilocalorie" with symbol "kcal". It is mostly used to express the amount of energy released in a chemical reaction or phase change, typically per mole of substance, as in kilocalories per mole.[32] It is also occasionally used to specify other energy quantities that relate to reaction energy, such as enthalpy of formation and the size of activation barriers.[33] However, it is increasingly being superseded by the SI unit, the joule (J); and metric multiples thereof, such as the kilojoule (kJ).

The lingering use in chemistry is largely due to the fact that the energy released by a reaction in aqueous solution, expressed in kilocalories per mole of reagent, is numerically close to the concentration of the reagent, in moles per liter, times the change in the temperature of the solution, in kelvin or degrees Celsius. However, this estimate assumes that the volumetric heat capacity of the solution is 1 kcal/L/K, which is not exact even for pure water.

See also

References
  1. Christopher W. Morris (1992) Academic Press Dictionary of Science and Technology. 2432 pages. ISBN 9780122004001
  2. Allison Marsh (2020): "How Counting Calories Became a Science: Calorimeters defined the nutritional value of food and the output of steam generators" Online article on the IEEE Spectrum website, dated 2020-12-29. Accessed on 2022-01-20.
  3. "Definition of Calorie". Merriam-Webster. August 1, 2017. Retrieved September 4, 2017.
  4. "Cambridge Dictionary: calorie". Retrieved November 9, 2019.
  5. "Definition of calorie noun from the Oxford Advanced American Dictionary". Retrieved November 9, 2019.
  6. U. S. Food and Drug Administration (2019): "Calories on the Menu - Information for ". Online document at the FDA Website, dated 2019-08-05. Accessed on 2022-01-20.
  7. U. K. National Health Service (2019): "What should my daily intake of calories be?". Online document at the NHS website, dated 2019-10-24. Accessed on 2022-01-20.
  8. Conn, Carole; Len Kravitz. "Remarkable Calorie". University of New Mexico. Retrieved 1 March 2019.
  9. Bureau International des Poids et Mesures (2019): The International System of Units (SI), 9th edition.
  10. Bureau International des Poids et Mesures (1998): The International System of Units (SI), 7th edition.
  11. United Nations Food and Agriculture Organization (2003): "FAO Food and Nutrition Paper 77: Food energy - methods of analysis and conversion factors". Accessed on 2022-01-21.
  12. Allain, Rhett (February 23, 2016). "Calculating Calories by Burning Gummy Bears to Death". Scientific American. Retrieved September 7, 2017.
  13. Hargrove, James L (2007). "Does the history of food energy units suggest a solution to "Calorie confusion"?". Nutrition Journal. 6 (44): 44. doi:10.1186/1475-2891-6-44. PMC 2238749. PMID 18086303.
  14. JL Hargrove, "history of the calorie in nutrition", J Nutr 136/12 (December 2006), pp. 2957–2961.
  15. Joseph Howard Raymond (1894): A Manual of Human Physiology: Prepared with Special Reference to Students of Medicine. W.B. Saunders, 376 pages.
  16. Marks, Percy L. (January 14, 1928). "The Two Calories, Percy L. Marks". Nature. 121 (3037): 58. doi:10.1038/121058d0. S2CID 4068300.
  17. 9th CGPM, Resolution 3: Triple point of water; thermodynamic scale with a single fixed point; unit of quantity of heat (joule)., bipm.org.
  18. International Standard ISO 31-4: Quantities and units, Part 4: Heat. Annex B (informative): Other units given for information, especially regarding the conversion factor. International Organization for Standardization, 1992.
  19. Rossini, Fredrick (1964). "Excursion in Chemical Thermodynamics, from the Past into the Future". Pure and Applied Chemistry. 8 (2): 107. doi:10.1351/pac196408020095. Retrieved 21 January 2013. both the IT calorie and the thermochemical calorie are completely independent of the heat capacity of water.
  20. Lynch, Charles T. (1974). Handbook of Materials Science: General Properties, Volume 1. CRC Press. p. 438. ISBN 9780878192342. Retrieved 8 March 2014.
  21. FAO (1971). "The adoption of joules as units of energy".
  22. International Union of Pure and Applied Chemistry (IUPAC) (1997). "1.6 Conversion tables for units" (PDF). Compendium of Analytical Nomenclature (3 ed.). ISBN 0-86542-615-5. Retrieved 31 August 2013.
  23. "Prospects improve for food energy labelling using SI units". Metric Views. UK Metric Association. 24 February 2012. Retrieved 17 April 2013.
  24. "SI Conventions". National Physical Laboratory. Retrieved 8 February 2016.
  25. Kevin T. Patton; Gary A. Thibodeau (11 January 2017). The Human Body in Health & Disease - E-Book. Elsevier Health Sciences. p. 537. ISBN 978-0-323-40206-4.
  26. "EU Regulation No 1169/2011 of the European Parliament and of the Council of 25 October 2011 on the provision of food information to consumers". eur-lex.europa.eu. Retrieved 2022-04-18.
  27. Nutrition, Center for Food Safety and Applied (2022-03-07). "Changes to the Nutrition Facts Label". FDA.
  28. USDA (2013). "China, General Rules for Nutrition Labeling of Prepackaged Foods" (PDF). Retrieved 2022-04-18.
  29. "How Do Food Manufacturers Calculate the Calorie Count of Packaged Foods?". Scientific American. Retrieved 2017-09-08.
  30. "Calories - Fat, Protein, Carbohydrates, Alcohol. Calories per gram".
  31. Strychar, I. (2006-01-03). "Diet in the management of weight loss". Canadian Medical Association Journal. 174 (1): 56–63. doi:10.1503/cmaj.045037. ISSN 0820-3946. PMC 1319349. PMID 16389240.
  32. Zvi Rappoport ed. (2007), "The Chemistry of Peroxides", Volume 2 page 12.
  33. Bhagavan, N. V. (2002). Medical Biochemistry. Academic Press. pp. 76–77. ISBN 9780120954407. Retrieved 5 September 2017.
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