Study (open access): Universal and efficient extraction of lithium for lithium-ion battery recycling using mechanochemistry

>Abstract

>The increasing lithium-ion battery production calls for profitable and ecologically benign technologies for their recycling. Unfortunately, all used recycling technologies are always associated with large energy consumption and utilization of corrosive reagents, which creates a risk to the environment. Herein we report a highly efficient mechanochemically induced acid-free process for recycling Li from cathode materials of different chemistries such as LiCoO2, LiMn2O4, Li(CoNiMn)O2, and LiFePO4. The introduced technology uses Al as a reducing agent in the mechanochemical reaction. Two different processes have been developed to regenerate lithium and transform it into pure Li2CO3. The mechanisms of mechanochemical transformation, aqueous leaching, and lithium purification were investigated. The presented technology achieves a recovery rate for Li of up to 70% without applying any corrosive leachates or utilizing high temperatures. The key innovation is that the regeneration of lithium was successfully performed for all relevant cathode chemistries, including their mixture.

I don't know enough about this to know if a 70% recovery rate is good. What is the recovery rate with current technology? This sounds promising, but can it be scaled?

But those are lithium primary cells.

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